ARP is used to find an ethernet MAC address belonging to an IPv4 address on your local LAN.
If you are sending packets to something that is not on your local LAN (according to the information that your PC has) your PC will send it to the default gateway, who is assumed to know what to do with it.
So, if you send something to an non-LAN destination your PC needs the MAC address of the default gateway, which it will send an ARP request for if it doesn't have it cached yet.
It is not possible to see MAC addresses of machines not on your local LAN.