You seem to be referring to 10GBASE-T. 10GBASE-R variants use 64b66b PCS encoding at 10.325 GBd.
Basically, 10GBASE-T uses PAM-16 signalling = 16 discrete voltage levels - theoretically representing four bits of information. Two consecutive signal levels are combined in a two-dimensional checkerboard DSQ128 pattern for seven bits of information. These are split over the four twisted pairs = four lanes at 800 MBd each, requiring a spectral bandwidth of only 400 MHz.
This is a simplified view, the complete encoding scheme is quite complex, check IEEE 802.3 Clause 55. The overview:
The 10GBASE-T PHY employs full duplex baseband transmission over four
pairs of balanced cabling. The aggregate data rate of 10 Gb/s is
achieved by transmitting 2500 Mb/s in each direction simultaneously on
each wire pair, as shown in Figure 55–2. Baseband 16-level PAM
signaling with a modulation rate of 800 Megasymbol per second is used
on each of the wire pairs. Ethernet data and control characters are
encoded at a rate of 3.125 information bits per PAM16 symbol, along
with auxiliary channel bits. Two consecutively transmitted PAM16
symbols are considered as one two-dimensional (2D) symbol. The 2D
symbols are selected from a constrained constellation of 128 maximally
spaced 2D symbols, called DSQ128 (double square 128). After link
startup, PHY frames consisting of 512 DSQ128 symbols are continuously
transmitted. The DSQ128 symbols are determined by 7-bit labels, each
comprising 3 uncoded bits and 4 LDPC-encoded bits. The 512 DSQ128
symbols of one PHY frame are transmitted as 4 × 256 PAM16 symbols over
the four wire pairs. Data and Control symbols are embedded in a
framing scheme that runs continuously after startup of the link. The
modulation symbol rate of 800 Msymbols/s results in a symbol period of
1.25 ns.