Like Eric stated, you need to add routes on both sides. You can do that by either having default routes pointing to each other via the /30 you're already using, or you can add routes for each host/subnet separately to go over the /30. You could add more dynamic routing over that serial connection, too, if you don't want to maintain static routes or use default routes.
For example, on R4, you could add: ip route 0.0.0.0 0.0.0.0 202.20.0.1 and on RD you could add: ip route 0.0.0.0 0.0.0.0 202.20.0.2.
As for whether all of the routers could reach each other (not just RD to/from R4), that depends on how your other routers route their traffic. If RD has valid paths to the other routers in the EIGRP AS and visa-versa, and R4 has valid paths to the other routers in the OSPF area(s) and visa-versa, and all of their subnets/hosts are part of the route statements that you set to traverse the serial interfaces via that /30 segment, then it should all work.